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Magnetic exchange interaction in amide complexes of uranium (IV) tetrachloride

✍ Scribed by Chie Miyake; Yukio Hinatsu; Shosuke Imoto

Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 179 KB
Volume: 63
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(79)80706-x

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✦ Synopsis

maxima at 135 and 142 L on the magnetic susceptxb&t> -tempemture curw, respectively+ Accurding to the Heisenbers model 2Jek Is obtained to be -94 and -99 cm-l, respectivelel). While magnetic exchange interaction in transition metal complexes has been extensively studied, uranium complex with such an exchange interaction has not yet been found in spite of much interest of chemists wncerning with actinide complexes_ Structures of tetrahis (diethy~mido) uranhrm (IV), U fN(C2Hs)2] 4, and tris [bis~~'-dimethy~ethylenediamido)l uranium (IV),

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