A novel layered zinc+cobalt phosphate Zn (2Ψx) Co x (HPO 4 ) 3 ' C 3 N 2 H 12 (x:0.05), has been solvothermally synthesized, and its structure determined at 293 K with a Siemens Smart 1000 CCD di4ractometer [monoclinic, P2 1 /c, a β«Ψβ¬ 8.632(2) A > , b β«Ψβ¬ 9.648(4) A > , c β«Ψβ¬ 17.077(6) A > , β«Ψβ¬ 93.
Magnetic structures of [Co3(pyz)(HPO4)2F2], a fluorinated cobalt phosphate with a pillared layer structutre
β Scribed by C.C. Yang; S.F. Lee; Y.D. Yao; W.-H. Li; K.H. Lii; J.W. Lynn
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 140 KB
- Volume
- 378-380
- Category
- Article
- ISSN
- 0921-4526
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π SIMILAR VOLUMES
## MIL-21 or [Fe III 5Ψx V III x (H 2 PO 4 ) 4 (HPO 4 ) 4 F 4 (H 2 O) 2 , 4(H 2Ψy N+ (CH 2 ) 2 +NH 2Ψy )] was prepared hydrothermally (453 K, autogenous pressure, 3 days) in the presence of ethylenediamine. Its structure was determined by single-crystal X-ray di4raction. MIL-21 is tetragonal (spac
3 d). The structure of the compound is determined at 150 and 295 K on a twinned crystal (trigonal, space group P3c1, Z = 4). Na 7 [Mn 5 F 13 (PO 4 ) 3 (H 2 O) 3 ] contains anionic layers formed by triangular units of three [MnF 3 O 2 (H 2 O)] octahedra sharing one Β΅ 3 -F atom and bridged by three ph