ChemInform Abstract: A Fluoride Phosphate of Manganese(III) with Unusual Layer Structure: Na7 [Mn5F13(PO4)3 (H2O)3].
β Scribed by R. STIEF; C. FROMMEN; J. PEBLER; W. MASSA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
3 d). The structure of the compound is determined at 150 and 295 K on a twinned crystal (trigonal, space group P3c1, Z = 4). Na 7 [Mn 5 F 13 (PO 4 ) 3 (H 2 O) 3 ] contains anionic layers formed by triangular units of three [MnF 3 O 2 (H 2 O)] octahedra sharing one Β΅ 3 -F atom and bridged by three phosphate groups. Stacking of these a,b-layers produces channels along the c-axis in which most of the Na + ions are located. The magnetic properties (Β΅ ef f = 4.61 Β΅ B ; T N = 3.3 K) are determined and possible magnetic exchange pathways are discussed.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v