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ChemInform Abstract: A Fluoride Phosphate of Manganese(III) with Unusual Layer Structure: Na7 [Mn5F13(PO4)3 (H2O)3].

✍ Scribed by R. STIEF; C. FROMMEN; J. PEBLER; W. MASSA


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


3 d). The structure of the compound is determined at 150 and 295 K on a twinned crystal (trigonal, space group P3c1, Z = 4). Na 7 [Mn 5 F 13 (PO 4 ) 3 (H 2 O) 3 ] contains anionic layers formed by triangular units of three [MnF 3 O 2 (H 2 O)] octahedra sharing one Β΅ 3 -F atom and bridged by three phosphate groups. Stacking of these a,b-layers produces channels along the c-axis in which most of the Na + ions are located. The magnetic properties (Β΅ ef f = 4.61 Β΅ B ; T N = 3.3 K) are determined and possible magnetic exchange pathways are discussed.


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