2 O 7 . Both the real part and the imaginary part of the ac susceptibilities are independent of frequency, indicating that these compounds are not in the ordinary spin-glass. Similar large jumps of speci5c heat are observed at 162, 143, 124, and 118 K for R 2 Ru 2 O 7 (R โซุโฌ Pr, Nd, Sm, and Eu). For
Magnetic Properties of Ruthenium Pyrochlores Y2Ru2O7and Lu2Ru2O7
โ Scribed by Nobuyuki Taira; Makoto Wakeshima; Yukio Hinatsu
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 105 KB
- Volume
- 144
- Category
- Article
- ISSN
- 0022-4596
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โฆ Synopsis
Magnetic susceptibility and magnetic hysteresis measurements were performed for Y 2 Ru 2 O 7 and Lu 2 Ru 2 O 7 , which show magnetic transitions at 80 and 85 K, respectively. Below the transition temperatures, there is a large difference in the temperature dependence of the magnetization measured between under zero-field cooled condition and under field-cooled condition, but no magnetic hysteresis has been observed. These results suggest that below the temperatures, both Y 2 Ru 2 O 7 and Lu 2 Ru 2 O 7 transform to a spin-glass state which is independent of the applied magnetic field.
๐ SIMILAR VOLUMES
The enthalpy increments of Y Si O and Dy Si O have been measured by drop-calorimetry 2 2 7 2 2 7 ลฝ . ลฝ . from T s 516.7 to 928.4 K, and T s 516.7 to 918.2 K, respectively. The standard molar enthalpy of formation of monoclinic Y Si O has been deduced from its enthalpy of solution 2 2 7 . y3 . y3 T ลฝ
The metal-versus-semiconductor behavior of ruthenium pyrochlores A 2 Ru 2 O 7ุy was examined by calculating their electronic band structures. This behavior is explained in terms of the Mott-Hubbard mechanism of electron localization. The width of the t 2g -block bands of A 2 Ru 2 O 7ุy increases wit
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