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Magnetic properties of 9,9-disubstituted 9,10-dihydroacridine-10-yloxyls

✍ Scribed by M. Seino; Y. Akui; T. Ishida; T. Nogami

Book ID: 117539095
Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 133 KB
Volume: 133-134
Category: Article
ISSN: 0379-6779
DOI: 10.1016/s0379-6779(02)00353-3

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## Abstract Hydrogen is transferred from acridane (1c) and __N__‐methylacridane (1d) to α‐methyl‐styrene (2) in a bimolecular uncatalyzed reaction at 260–300°C. On the basis of the activation parameters (for 1c: Δ__H__^≠^ = 29.0 kcal/mol, Δ__S__^≠^ = −23.5 e.u. in triglyme) the kinetic isotope effe