Alkohol umkrystallisiert werden. Rie im folgenden erwahnten Ausbeuten beziehen sich immer auf Priiparate mit dem richtigen Schmelzpunkt (laso). ## Es wurden erhalten: 1. Ane 6,99 gr 16dicher Stiirke (66% Trockemubstanz) 0,3 gr @-Methyl-heptacetyl-21 Aus 6 , b gr liielicher Stiirke (69% Trockeneub
Benzyl group migration in 9-Methyl-10-benzyl-9,10-Dihydroacridine
β Scribed by George A. Digenis
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 374 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0022-3549
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π SIMILAR VOLUMES
S-Benzyl-lo-aza-S-thiaphenanthrenes (3) generated from S-benzyl-lO-aza-Sthiaphenanthrenium salts (2) by treatment with base underwent thermal 1,2-benzyl migration to give the corresponding 6-benzyl-GH-dibenzo[c,e]11,2lthiazines (4).
## Abstract Hydrogen is transferred from acridane (1c) and __N__βmethylacridane (1d) to Ξ±βmethylβstyrene (2) in a bimolecular uncatalyzed reaction at 260β300Β°C. On the basis of the activation parameters (for 1c: Ξ__H__^β ^ = 29.0 kcal/mol, Ξ__S__^β ^ = β23.5 e.u. in triglyme) the kinetic isotope effe
Absmce Readm c@-arykthylene-llLwa&yl-9,IO~~ (1) w&h more rhan hw, eqvivolcnrJ qf m-choloropao&ensolc add in C&C&? i#w& lWmdby /Mydmxy-tedory~kyl jxroqwa (5) dewmposing to N-methylactiiae and aronmuic aldehyde math chemiluminescence by a ClEhZ mechanism Applications of chemihuninescence (CL) and biol