A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid

✍ Scribed by Katsumasa Sakanishi; Mohamad Bambang Nugroho; Yoshiyuki Kato; Natsuki Yamazaki

• Publisher: Elsevier Science
• Year: 1994
• Tongue: French
• Weight: 333 KB
• Volume: 35
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)73237-0

✦ Synopsis

Absmce Readm c@-arykthylene-llLwa&yl-9,IO~~ (1) w&h more rhan hw, eqvivolcnrJ qf m-choloropao&ensolc add in C&C&? i#w& lWmdby /Mydmxy-tedory~kyl jxroqwa (5) dewmposing to N-methylactiiae and aronmuic aldehyde math chemiluminescence by a ClEhZ mechanism Applications of chemihuninescence (CL) and bioluminescence in analytical chemistry have amacted considerable interest in recent years. 1 We have recently found CL during the epoxidation of 9-a@methylene-lO-methyl-9,lOdih~e (1)2 with m-chloroperoxybenxoic acid (MCPBA), dimethyldioxirane, and hydroperoxides. As far as we know, CL in the reaction of olefiu with peroxides is unprecedented. We report here about a novel CL ftom the reaction of 1 with MCPBA, and suggest its plausible mechanism.