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Magnetic properties and electronic structures of CrMZ (M  Fe, Co, Ni; Z  P, As)

✍ Scribed by S Ishida; T Takiguchi; S Fujii; S Asano


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
603 KB
Volume
217
Category
Article
ISSN
0921-4526

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✦ Synopsis


Electronic structures of the compounds CrMZ (M = Fe, Co, Ni, Z = P, As) were calculated to examine the magnetic properties. From the density of state for a nonmagnetic state, we can guess that Cr in CrMZ carries a magnetic moment but the M atom does not even though pure metals of Fe, Co and Ni are ferromagnets. It will also be shown that although the M atom is nonmagnetic, the magnetism of CrMZ changes with the M atom because the hybridization between the d states of the Cr and M atom affects the Cr d bands. These are confirmed by the total energies and electronic structures for the ferro-and antiferromagnetic states.


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