Electronic structure and magnetism of Y-M (M=Mn, Fe, Co and Ni) compounds
β Scribed by J. Inoue
- Publisher
- Elsevier Science
- Year
- 1988
- Weight
- 966 KB
- Volume
- 149
- Category
- Article
- ISSN
- 0378-4363
No coin nor oath required. For personal study only.
β¦ Synopsis
Various magnetic properties observed in Y-M (M=Mn, Fe, Co and Ni) and Y2Ma4 B (M=Fe and Co) intermetallic compounds are reviewed from a viewpoint of the itinerant electron model. The characteristics of the electronic density of states calculated for these compounds are summarised. It is shown that the general trend of the magnetism of these compounds can be explained in terms of the calculated results of the density of states. The calculated values of the low-temperature specific heat coefficient and the local magnetic moments show good agreement with the experimental ones, which confirms the validity of the explanation of their magnetism in terms of the itinerant electron model. Explanations are given for the large magnetovolume effect in Fe-rich Y-Fe compounds, the metamagnetism of Y2Ni16, the thermal spontaneous ferromagnetism of Y2Ni 7 and the weak ferromagnetism of Y9C07.
π SIMILAR VOLUMES
Electronic structures of the compounds CrMZ (M = Fe, Co, Ni, Z = P, As) were calculated to examine the magnetic properties. From the density of state for a nonmagnetic state, we can guess that Cr in CrMZ carries a magnetic moment but the M atom does not even though pure metals of Fe, Co and Ni are f
Density functional theory (DFT) calculations of the electronic structure and properties of Fe, Ni, and Cu carbonyls with one and five transition-element atoms are reported, due to their importance in heterogeneous catalysis (especially in Fischer-Tropsch synthesis). The local density approximation (
Electronic structures of the binary compound YCo, and the ordered ternary compounds Y(Co,\_,Al,), and Y(Co,\_,Si,), with the cubic Laves structure are calculated within the density functional theory. It is shown that the magnetic properties observed in the recent experiments, such as induced weak fe