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Magnetic Interactions in Two Heterobridged Dinuclear Copper(II) Complexes: Orbital Complementarity or Countercomplementarity?

✍ Scribed by Wang, Li-Li; Sun, You-Min; Qi, Zhong-Nan; Liu, Cheng-Bu

Book ID: 121313869
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 617 KB
Volume: 112
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp8044252

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with