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Supramolecular Hydrogen-Bond Structures and Magnetic Interactions in Basal-Apical, Dinuclear, Azide-Bridged Copper(II) Complexes

✍ Scribed by Mau Sinha Ray; Ashutosh Ghosh; Siddhartha Chaudhuri; Michael G. B. Drew; Joan Ribas

Publisher: John Wiley and Sons
Year: 2004
Tongue: English
Weight: 190 KB
Volume: 2004
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200300969

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with