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Magnetic interactions in a vanadyl complex of an iminonitroxide radical

✍ Scribed by Paul F. Richardson; Robert W. Kreilick

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 258 KB
Volume: 50
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80194-2

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✦ Synopsis

We have synthesizd a complex in which a pyridyhminonitroxldc radical is Loordmated to r\ vanadyl IOIL ESR studies of thts complex show that the radical's unpaired spin is tightly coupled to the vanadium spin to form a ground singlet state with a thermaily acce,stble trlplct s'tiltc. Tbc vanadium hyperfinc splittmg in the triplet state of the complex is found to be one half of that of isolated vanadyl complexes.

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