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Synergy between Magnetic Interaction and Spin Crossover in an Iron(III) Complex with an Organic Radical as Ligand

✍ Scribed by Dr. Jean-Pascal Sutter; Dr. Mohammed Fettouhi; Licun Li; Dr. Cécile Michaut; Dr. Lahcéne Ouahab; Prof. Olivier Kahn


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
466 KB
Volume
35
Category
Article
ISSN
0044-8249

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✦ Synopsis


0 r( \ L.

[14] ( + ) -7 has the absolute configuration p(R) [ll]. As only part of 2 is racemized during the conversion from 7, it must be concluded that ( --)-Z and ( + ) -2 have the configurations p(R) and p(S), respectively. 1151 From p(R)-( +)-7, p(R)-( -)-2 is formed in the monomer synthesis. and (+)-I is formed from this by polycondensation and a polymer-analogous cyclization. 1161 The molar optical rotation of ( + ) -I is 594rddcm2damol-' [17] B.


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