The theory of magnetic field effects (MFEs) on geminate recombination of highly anisotropic radicals is developed taking into account the anisotropy of reactivity, exchange and electrostatic interactions. Simple analytical expressions for the optically detected MFE amplitude Ps and the CIDEP P, are
Magnetic field modulation of geminate recombination of radical ions in a polar solvent
✍ Scribed by M.E. Michel-Beyerle; R. Haberkorn; W. Bube; E. Steffens; H. Schröder; H.J. Neusser; E.W. Schlag; H. Seidlitz
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 637 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The magnetic-field-dependent kinetics of geminate radical pairs, created by electron transfer from aniline fo rhionine triplet in reversed micelles has been studied by nanosecond laser flash spectroscopy. Dependin, = on the water concentration, the rate constant of intrarnicek recombination is reduc
The magnetic field effect on pyrenefN,Nðylamline steady-state exciplex fluorescence was found to depend on solvent polarity. It is explained in terms of a model based on macroscopic properties of the system. Potential barriers between radical ion pair state and fluorescent exciplex, E, = 0.18-0.2