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Magnetic field effects on the reactivity of co-ordination complexes: a probe of the transition-state magnetic properties in outer-sphere electron transfers

โœ Scribed by Ronco, S.; Ferraudi, G.

Book ID
120661165
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
384 KB
Volume
3
Category
Article
ISSN
1472-7773

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The effect of a magnetic field on outer-
The effect of a magnetic field on outer-sphere electron transfer
โœ A.I. Ivanov; V.A. Mikhaylova ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 355 KB

The magnetic field influence on the outer-sphere electron transfer rate is analyzed within the framework of a dynamical model including exchange interaction between the transferred electron and a paramagnetic centre placed in the vicinity of an acceptor. It is shown that the rate can vary by 20%-30%