Magnetic circular dichroism studies. XII. Determination of tryptophan in proteins
β Scribed by Djerassi, Carl; Barth, Guenter; Records, Ruth; Bunnenberg, Edward; Voelter, Wolfgang
- Book ID
- 126008995
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 340 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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Two spectral features are observed for the magnetic circular dichroism (MCD) spectra of 1,4-diazabicyclo-[2.2.2]octane (DABCO) in solution. First an intense positive A term is revealed in the range of 250-200 nm which provides an unambiguous assignment for a degenerate 'E' state. The energy at which
An UV absorption and CD study of intestinal fatty acid-binding protein is presented. Since there are only two Trp residues in the molecule, two single-Trp mutants were prepared to deconvolute their signals. The individual contribution of the eight Phe and four Tyr residues was not established; howev