Magnetic Characteristics of ErCo10Mo2-xVx Family of Compounds.
โ Scribed by A. Elmali; A. Yuecel; E. Duman; Y. Elerman
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 9 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
An ampule reaction between Mo and PCl 5 at 200 ยฐC yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in MoยฑPยฑCl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A ร , ฮฑ = 100.24(2), b = 95.55(2), c = 96.12(2)ยฐ(V = 559.3(2) A ร 3
Na 2 M Si 4 O 10 (M โซุโฌ Co, Ni) compounds have been obtained by annealing at 700ยฐC a xerogel prepared from silicon and sodium ethoxides and M nitrate. Both silicates appear to be isostructural with the corresponding copper phase, with the presence of silicate pipes built up from (Si 8 O 20 ) 8ุ unit
Reinvestigation of the Rb+Mo+S system has led to the discovery of a novel family of reduced molybdenum sul5des with the general formula Rb 2n (Mo 9 S 11 )(Mo 6n S 6nุ2 ) (n โซุโฌ 1 to 4) in addition to the previously known compound Rb 2 Mo 6 S 6 . The new rubidium-reduced molybdenum sul5des have been