Magnetic and electrical properties of La0.67Ca0.33Mn0.9V0.1O3 two-phase composite
β Scribed by V.S. Kolat; H. Gencer; S. Atalay
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 493 KB
- Volume
- 371
- Category
- Article
- ISSN
- 0921-4526
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β¦ Synopsis
In this work, we present magnetic and electrical properties of La 0.67 Ca 0.33 Mn 1Γx V x O 3 (x ΒΌ 0 and 0.1). Polycrystalline La 0.67 Ca 0.33 MnO 3 and La 0.67 Ca 0.33 Mn 0.9 V 0.1 O 3 samples were prepared by conventional solid-state reaction. Two Curie temperatures for the La 0.67 Ca 0.33 Mn 0.9 V 0.1 O 3 sample were observed at T c1 ΒΌ 223 K and T c2 ΒΌ 190 K. The undoped La 0.67 Ca 0.33 MnO 3 sample showed only one magnetic transition temperature at 267 K. The temperature dependence of resistance showed two maxima in the V-doped sample, and the peak value of magnetoresistance (MR) around the Curie temperature increased with V doping. Double maxima in the resistance-temperature and magnetisation-temperature curves are explained by the existence of two phases in La 0.67 Ca 0.33 Mn 0.9 V 0.1 O 3 samples.
π SIMILAR VOLUMES
Orthorhombic perovskite-type (La 0.1 Ca 0.9 )(Mn 1Ψx Ge x )O 3 was synthesized in the range (0.004 4x4 40.10). Since the ionic radius of the Ge 4Ψ ion is equal to that of the Mn 4Ψ ion, the (Mn, Ge)-O(1, 2) distances and the angles for (Mn, Ge)-O(1, 2)-(Mn, Ge) are independent of the composition (x)