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Macromolecular engineering of polylactones and polylactides. XXI. Controlled synthesis of low molecular weight polylactide macromonomers

✍ Scribed by I. Barakat; Ph. Dubois; Ch. Grandfils; R. Jérôme


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
388 KB
Volume
34
Category
Article
ISSN
0887-624X

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Macromolecular engineering of polylacton
✍ I. Barakat; Ph. Dubois; Ch. Grandfils; R. Jérôme 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 217 KB

Well-defined ␣,-methacryloyl poly--caprolactone (PCL) and poly(D,L)-lactide P(D,L)LA dimacromonomers have been synthesized by living ring-opening polymerization of the parent monomers initiated by diethylaluminum 2-hydroxyethylmethacrylate (Et 2 AlOOO(CH 2 ) 2 OOOC(O)OC(CH 3 )ACH 2 ) and terminated