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Macroligand effect of tungsten catalyst for ring opening metathesis polymerization of dicyclopentadiene

✍ Scribed by Zheng Wang; Hong Li; Binglin He


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
362 KB
Volume
159
Category
Article
ISSN
1381-1169

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Ring-opening metathesis polymerization o
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Ž . Ž . Ring-opening metathesis polymerization ROMP of dicyclopentadiene DCPD was conducted by using catalyst systems Ž . WCl -Et AlCl, WCl -PhCOMe -Et AlCl and their polystyrene supported counterparts. Experimental results indicate that 6 2 6 2 the acetophenone modified catalyst system shows bette

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## Abstract The ring‐opening metathesis polymerization of cyclododecene using an electrochemically reduced tungsten‐based catalyst (WCl~6~e^−^AlCH~2~Cl~2~) is described. In addition, the influence of reaction conditions on the polymerization yield was determined. The resulting polymer has been c