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Applications of chloro-aryloxide complexes of tungsten in olefin metathesis: The ring-opening metathesis polymerization of dicyclopentadiene

✍ Scribed by Djaber Boutarfa; Christophe Paillet; Michel Leconte; Jean-Marie Basset

Publisher
Elsevier Science
Year
1991
Weight
770 KB
Volume
69
Category
Article
ISSN
0304-5102

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Ring opening metathesis polymerization o
Ring opening metathesis polymerization of dicyclopentadiene catalyzed by titanium tetrachloride adduct complexes with nitrogen-containing ligands
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Ring opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD) catalyzed by titanium tetrachloride adduct complexes such as TiCl 4 ⅐ 2L [L ϭ pyridine (1), 2-methylpyridine (2), 2,4,6-trimethylpyridine (3), 3-aminopyridine (4), 2-hyroxypyridine (5)] and CH 3 Li as cocatalyst was reported.

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Ring-opening metathesis polymerization of dicyclopentadiene catalyzed by titanium tetrachloride adduct complexes with oxygen-containing ligands
✍ Yanlong Qian; Keleypette Dono; Jiling Huang; Haiyan Ma 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 112 KB 👁 2 views

## Abstract Ring‐opening metathesis polymerization of dicyclopentadiene catalyzed by TiCl~4~ · 2L/CH~3~Li system [where L is tetrahydropyran (1), dioxane, 2,5‐dimethylfuran, or tetrahydrofurfyl alcohol] is reported. The obtained polymer was characterized by IR and ^1^H‐NMR. These catalytic systems