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Polymerizability of cycloalkenes in a living ring-opening metathesis polymerization initiated by Schrock complexes, 1. Effect of the solvent on the polymerization kinetics

✍ Scribed by Chrystelle Cazalis; Valérie Héroguez; Michel Fontanille


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
112 KB
Volume
201
Category
Article
ISSN
1022-1352

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Ring-opening polymerization of 1,5-dioxepan-2-one initiated by 1,1,6,6tetra-n-butyl-1,6-distanna-2,5,7,10-tetraoxacyclodecane was carried out in chloroform, dichloromethane, or 1,2-dichloroethane. Effects of reaction temperature, solvent, and monomer-to-initiator ratio were investigated. Polymerizat