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Macrocyclic oxonium ylide formation and internal [2,3]-sigmatropic rearrangement. Catalyst influence on selectivity

✍ Scribed by Michael P. Doyle; Chad S. Peterson

Book ID: 104257516
Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 198 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)01160-x

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✦ Synopsis

The formation of 13-membered ring oxonium ylides and their subsequent stereocontrolled [2,3]-sigmatropic rearrangement to l O-membered ring lactones occurs in catalyst dependent competition with macrocyfic cyclopropanation.

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