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ChemInform Abstract: Enantioselective [2,3]-Sigmatropic and [1,2]-Stevens Rearrangements via Intramolecular Formation of Allylic Oxonium Ylides Catalyzed by Chiral Dirhodium(II) Carboxylates.

✍ Scribed by Shinji Kitagaki; Yoshimasa Yanamoto; Hideyuki Tsutsui; Masahiro Anada; Makoto Nakajima; Shunichi Hashimoto

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200145121

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of α-Methoxycarbonyl-α-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy