Macrocyclic Diketopiperazine Receptors: Effect of Macrocyclization on the Binding Properties of Two-Armed Receptors
β Scribed by Bernard, Jessica; Wennemers, Helma
- Book ID
- 127136534
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 132 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1523-7060
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π SIMILAR VOLUMES
Macrocyclic receptor 1 has been synthesised, as a racemate and as a single enantiomer, utilising a Stille coupling for the formation of the biphenyl portion and a macrolactamisation as the final step. The binding properties for the racemic and the homochiral macrocycle with amino acid and dipeptide
## Abstract magnified image Neutral classes of amideβbased macrocycle have been synthesized and the anion binding abilities are assessed by UVβvis titration and ^1^H nmr experiments. Results indicate that higher anion binding abilities are observed for H~2~PO~4~^β^, F^β^ and AcO^β^, but almost no