Lyngbyaloside, a Novel 2,3,4-Tri- O -methyl-6-deoxy-α-mannopyranoside Macrolide from Lyngbya bouillonii (Cyanobacteria)
✍ Scribed by Klein, D.; Braekman, J. C.; Daloze, D.; Hoffmann, L.; Demoulin, V.
- Book ID
- 125974316
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 117 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0163-3864
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Syntheses of the pentasaccharide 2-(4-aminophenyl)ethyl 3-deoxy-5-O-(3,4,6- tri-O-beta-D-glucopyranosyl-alpha-D-glucopyranosyl)-alpha-D-manno-oct-2- ulopyranosidonic acid and of the tetrasaccharide 3,4,6-tri-O-beta-D-glucopyranosyl-alpha-D-glucopyranoside, both as its methyl and 2-(4-trifluoro-aceta
X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th