Acylated ]3-o-xylopyranose derivatives are known to exist as a mixture of the 1C 4 and 4C I conformers in rapid equilibrium in solution [3]. Several conformations have also been reported for/3-D-xylopyranose derivatives in the solid state [4]. In the course of our study to investigate the functions
ChemInform Abstract: Synthetic Studies on Oligosaccharides of a Glycolipid from the Spermatozoa of Bivalves. Part 11. Molecular and Crystal Structure of Methyl 2,3,4-Tri-O-acetyl-β-D-xylopyranosyl-(1 → 2)-3-O- benzyl-4,6-O-benzylidene-α-D-mannopyranoside.
✍ Scribed by O. KANIE; T. TAKEDA; K. HATANO
- Book ID
- 112028371
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Both 'H-and 13C-n.m.r. spectroscopy have been employed in structural studies of the 4,6-O-benzylidene-D-aldohexopyranosides and derivatives, including some deoxy sugars . I4 We now report i3C-n.m.r. data (Table I) for the 4,6-O-benzylidene derivatives of methyl 2-deoxy-( 2) 2-deoxy-3-O-methyl-(3),
X-ray crystallographic analyses are reported for the two title compounds (8 and 9), of which the former crystallized in two modifications (8n and 8b). In all three structures, the pyranose rings have the %, (D) conformation and the substituents at C-l are axial and those at C-24-4 are equatorial. Th