✦ LIBER ✦

Luminescent behavior of soluble poly(para-phenylene vinylene) copolymers

✍ Scribed by B.J. Sun; Y.-J. Miao; G.C. Bazan; E.M. Conwell

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 415 KB
Volume: 260
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(96)00907-4

No coin nor oath required. For personal study only.

✦ Synopsis

Soluble diblocks with well-defined lengths of poly(phenylene vinylene), PPV, and an inert polymer, polynorbornene, PNBE, have been made by a new type of synthesis. For dilute solutions and relatively short lengths of PPV the quantum efficiency of luminescence is over 70% and the radiative lifetimes are 3 ns. We find that with increasing concentration of PPV in solution the luminescence efficiency decreases, which we propose is due to formation of polaron pairs.

📜 SIMILAR VOLUMES

Intermolecular Order of Poly-(2,5-dimeth

Intermolecular Order of Poly-(2,5-dimethyl-para-phenylene vinylene) and Poly-(para-phenylene vinylene) – A Comparison

✍ Roland Resel; Raf Kiebooms; Dirk Vanderzande; Franz Stelzer 📂 Article 📅 2001 🏛 Springer Vienna 🌐 English ⚖ 113 KB

A blue-luminescent ladder-type poly(para

A blue-luminescent ladder-type poly(para-phenylene) copolymer containing oxadiazole groups

✍ J. Grüner; R.H. Friend; J. Huber; U. Scherf 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 523 KB

We report investigations of electroluminescence and photoluminescence in a blue-luminescent soluble ladder-type para-phenylene copolymer, which contains additional segments of 2-phenyl-5-(4-biphenyl)-l,3,4-oxadiazole (PBD) groups in the polymer main chain. The PBD segments and the ladder-type copoly

Annihilation Dynamics of the Luminescenc

Annihilation Dynamics of the Luminescence in Oriented Poly-(p-Phenylene Vinylene)

✍ P. Haring Bolivar; G. Wegmann; G. Leising; H. Kurz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 168 KB 👁 2 views

Structural characterization and luminesc

Structural characterization and luminescent properties of poly(p-phenylene vinylene) and poly(ethylene glycol) blends

✍ Horng-Long Cheng; King-Fu Lin 📂 Article 📅 1999 🏛 Springer 🌐 English ⚖ 601 KB

A soluble poly(para-phenylene) composed

A soluble poly(para-phenylene) composed of cyclophane units: Poly[2,5-(oxydecanoxy)-1,4-phenylene]

✍ Joachim Huber; Ullrich Scherf 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 300 KB

Conjugated copolymers of cyanosubstitute

Conjugated copolymers of cyanosubstituted poly(p-phenylene vinylene) with phenylene ethynylene and thienylene vinylene moieties: Synthesis, optical, and electrochemical properties

✍ Yingping Zou; Bo Peng; Bo Liu; Yongfang Li; Yuehui He; Kechao Zhou; Chunyue Pan 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 227 KB 👁 1 views

## Abstract Three alternating conjugated copolymers of cyanosubstituted poly(__p__‐phenylene vinylene) (CN–PPV) with phenylene ethynylene and thienylene vinylene moieties, **P1, P2,** and **P3,** were synthesized via cross‐coupling polycondensation with Pd(PPh~3~)~2~Cl~2~ as a catalyst. Their struc