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Intermolecular Order of Poly-(2,5-dimethyl-para-phenylene vinylene) and Poly-(para-phenylene vinylene) – A Comparison

✍ Scribed by Roland Resel; Raf Kiebooms; Dirk Vanderzande; Franz Stelzer


Publisher
Springer Vienna
Year
2001
Tongue
English
Weight
113 KB
Volume
132
Category
Article
ISSN
0026-9247

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Soluble diblocks with well-defined lengths of poly(phenylene vinylene), PPV, and an inert polymer, polynorbornene, PNBE, have been made by a new type of synthesis. For dilute solutions and relatively short lengths of PPV the quantum efficiency of luminescence is over 70% and the radiative lifetimes

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The thermal behavior of poly(para-2,5-didecyl-p-phenylene) has been investigated by differential scanning calorimetry and real time X-ray diffraction. Poly(para-2,5-didecyl-p-phenylene) is a semicrystalline material that crystallizes in a layered structure. The system exhibits two thermal transition