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Lowest triplet state of substituted benzenes. II. Phosphorescence microwave double resonance studies on the 3.pi..pi.* state of p-dichlorobenzene

โœ Scribed by Buckley, M. J.; Harris, C. B.; Panos, R. M.

Book ID
126210463
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
987 KB
Volume
94
Category
Article
ISSN
0002-7863

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Assignment of the lowest triplet state o
Assignment of the lowest triplet state of benzene using phosphorescence-microwave double resonance (PMDR) techniques
โœ A.A. Gwaiz; M.A. El-Sayed; D.S. Tinti ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 322 KB

Phosphorescence-microwave double resonance (PMDR) techniques are wed and the zero-field (zf) origin of the 0,O band of the phosphorescence of benzene-& in benzene-& a.t 1.6% is determined to be the TY level. This is cuns;tent with a 3B1u assignment for a distorted D2h benzene in its triplet state an