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Low Temperature X-ray Crystallographic Structures of Two Lamotrigine Analogues: (I) 2-Methyl,3-amino, 5-imino-6-(2,3-dichlorophenyl)-1,2,4-triazine Water Solvate and (II) 2-Methyl,3,5-diamino-6-(2,3-dichlorophenyl)-1,2,4-triazine Isethionate, Hemi-hydrate

✍ Scribed by Rex A. Palmer; Brian S. Potter; Michael J. Leach; Babur Z. Chowdhry


Publisher
Springer
Year
2008
Tongue
English
Weight
246 KB
Volume
38
Category
Article
ISSN
1572-8854

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## Reactions of [(AMTTO)PdCl 2 ]•MeOH (1) with sodium bromide and sodium iodide led to the palladacycles [(AMTTO)PdBr 2 ] 2 •3.5THF (2) and [(AMTTO)PdI 2 ] 2 •3MeOH (3) in excellent yields. Treatment of 2 and 3 with triphenylphosphane gave the complexes [(AMTTO)Pd(PPh 3 )Br]-Br•MeOH (4) and [(AMTT