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Low-Temperature Tunneling in the Spin-State Relaxation Dynamics of Iron(III) Spin-Crossover Compounds

โœ Scribed by Schenker, Sabine; Hauser, Andreas


Book ID
126846408
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
186 KB
Volume
116
Category
Article
ISSN
0002-7863

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The high-spin โ†’ low-spin relaxation in spin-crossover compounds can be described as non-adiabatic multi-phonon process in the strong coupling limit, in which the low-temperature tunnelling rate increases exponentially with the zero-point energy difference between the two states. Based on the hypothe