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Metastable states at low temperature in spin crossover compounds in the framework of the atom-phonon coupling model

✍ Scribed by A. Gindulescu; A. Rotaru; J. Linares; M. Dimian; J. Nasser

Book ID
113856523
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
213 KB
Volume
30
Category
Article
ISSN
0277-5387

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The high-spin β†’ low-spin relaxation in spin-crossover compounds can be described as non-adiabatic multi-phonon process in the strong coupling limit, in which the low-temperature tunnelling rate increases exponentially with the zero-point energy difference between the two states. Based on the hypothe