✦ LIBER ✦

Low-Temperature Restructuring Processes in Polyhydrosilanes

✍ Scribed by Liviu Sacarescu; Angeliki Siokou; Rodinel Ardeleanu; Gabriela Sacarescu; Mihaela Simionescu

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 216 KB
Volume: 27
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.200600192

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Summary: This paper presents the structural influence of the SiH functionality on the physicochemical properties of polysilanes. New low‐temperature restructuring processes were discovered using thermal analysis (TGA, DSC). Photoluminescent (FL) and X‐ray photoelectron spectroscopy (XPS) measurements revealed the optoelectronic properties‐chemical structure relationship of the synthesized polymers.

Highly reactive SiH groups lead to restructuring of the main polysilane chain.

magnified imageHighly reactive SiH groups lead to restructuring of the main polysilane chain.

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