✦ LIBER ✦

Low lying optically active Rydberg transitions in propyleneimine

✍ Scribed by G. Gottarelli; B. Samorĭ; Alex F. Drake

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 349 KB
Volume: 45
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(77)80278-9

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✦ Synopsis

The circular dichroism spectrum of (-)-S-propyleneimine was recorded in the vapour phase and in hexane solution. SCF CI calculations of optical activity indicate that the absorption observed at ca. 50 000 cm-t corresponds to an n -3s Rydberg type transition. The possible nature of the next absorption is also discussed.

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