โ Scribed by J. Randell; S.L. Lunt; G. Mrotzek; D. Field; J.P. Ziesel
No coin nor oath required. For personal study only.
Low-energy resonances involving the 3~-, l A and 1)2,+ states of NO-have been studied by high-resolution electron scattering integrated over the angular range 60-120 ยฐ and in the energy range 0.07-1.6 eV. The resonant vibratiohal energies of the 3~-state yield agreement with the NO electron affinity of 24 meV determined from photodetachment itudies. The widths of the vibrational series 3~-and ]A increase slowly with the vibrational quantum number at v~riance with calculations.
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The electronic states of the unsaturated organometallic carbene CrCHz are investigated using high-resolution translational energy loss spectroscopy. The observed energy loss feature (1.05 +0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, 6B, and 6A,
Ab initio SCF and CI calculations employing a relatively large basis set including various polarization and diffuse (Rydberg-type) functions find the lowest-lying valence-shell state of CO? to be 5.14 eV less stable than carbon dioxide itself in the linear equilibrium geometry of the latter. Many lo