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Electronic states of chromium carbene ions characterized by high-resolution translational energy loss spectroscopy

✍ Scribed by M.A. Hanratty; E.A. Carter; J.L. Beauchamp; W.A. Goddard III; A.J. Illies; M.T. Bowers

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 337 KB
Volume: 123
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80064-1

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✦ Synopsis

The electronic states of the unsaturated organometallic carbene CrCHz are investigated using high-resolution translational energy loss spectroscopy.

The observed energy loss feature (1.05 +0.2 eV) is in good agreement with theoretical calculations which predict two higher lying states, 6B, and 6A, at 0.78 and 0.82 eV respectively, above the 4B, ground state of CrCH:.

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