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Low-barrier hydrogen bonds in proteins

✍ Scribed by Hosur, M. V.; Chitra, R.; Hegde, Samarth; Choudhury, R. R.; Das, Amit; Hosur, R. V.


Book ID
121307166
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
963 KB
Volume
19
Category
Article
ISSN
0889-311X

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High-level ab initio and DFT molecular orbital calculations have been used to investigate the physical properties of a model low-barrier hydrogen Ž . bond LBHB system: formic acid᎐formate anion. In the gas phase, it is found w that the hydrogen bond formed is extraordinarily short and strong ca. 27