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Low-Barrier Hydrogen Bonds and Enzymatic Catalysis

✍ Scribed by W.W. Cleland


Book ID
115568414
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
61 KB
Volume
382
Category
Article
ISSN
0003-9861

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Low-barrier hydrogen bonds:Abinitio and
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High-level ab initio and DFT molecular orbital calculations have been used to investigate the physical properties of a model low-barrier hydrogen Ž . bond LBHB system: formic acid᎐formate anion. In the gas phase, it is found w that the hydrogen bond formed is extraordinarily short and strong ca. 27