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Longitudinal lattice modes in linear mixed valence compounds

✍ Scribed by C.E. Paraskevaidis; C. Papatriantafillou

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
289 KB
Volume
58
Category
Article
ISSN
0009-2614

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✦ Synopsis

Mbed valence compounds of platinum or palladium have a crystal structure that consists of long, linear chains. The frequencies of the three coIktive (phonon) longitudinal k = 0 optical modes bear little xelevance to those of lon&udinaI modes of the independent mokcutes, being different in general and not in a one to one correspondence with them, l%eEefoze, tttey have to be taken into account as such when the observed intezxsity peaks in resonance Raman or infrared spectra of these coiupounds are analyzed.

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