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Interference transition dipole in mixed-valence compounds

โœ Scribed by Lucjan Dubicki; James Ferguson

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
402 KB
Volume
109
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

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Mbed valence compounds of platinum or palladium have a crystal structure that consists of long, linear chains. The frequencies of the three coIktive (phonon) longitudinal k = 0 optical modes bear little xelevance to those of lon&udinaI modes of the independent mokcutes, being different in general an

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A vibronic coupling model for mixed valence systems is outline& which permits explicit calculation of the absorption profile of the intervalence band. The model also predicts very low energy "tunneling' transitions which should be both observable and interesting.