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Long range electron transfer between tyrosine and tryptophan in hen egg-white lysozyme

✍ Scribed by Marcelo Weinstein; Zeev B. Alfassi; Michael R. DeFelippis; Michael H. Klapper; M. Faraggi


Book ID
113268441
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
497 KB
Volume
1076
Category
Article
ISSN
0167-4838

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Electrosynthesis provides a novel methodology to produce specific and selective chemical reaction in proteins. Thus electrooxidation of hen egg-white lysozyme (HEWL) at + 1.2 V (vs see) at a carbon anode in mildly acid buffer produces selective oxidation at methionine-105; while by increase in anodi