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Long-range deuterium isotope effects on 1H chemical shifts in some simple organometallic compounds

✍ Scribed by Yong-Cheng Wei; Peter R. Wells; Lynette K. Lambert

Publisher: John Wiley and Sons
Year: 1986
Tongue: English
Weight: 407 KB
Volume: 24
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1260240805

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✦ Synopsis

Proton NMR spectra are reported for chlorotrimethylstannane, tetramethylstannane, tetramethylplumbane and dimethylmercury containing various combinations of CH, and CD, groups. Additive long-range isotope effects on chemical shifts, 4AH(D), are observed to result in increased shielding of essentially the same magnitude in each case. There appears to be no significant isotope effect on the 'J coupling constant.

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