Long-lived 1-adamantaneimminyl free radical as studied by ESR in 1-cyanoadamantane

✍ Scribed by J.P. Michaut; J.J. Pinvidic; J. Roncin; H. Szwarc

• Book ID: 103024857
• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 240 KB
• Volume: 120
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)80554-6

✦ Synopsis

The prcducls of y-irraduabon of I-cyanoadnmnnranr were studled as n funcuon of tcmpsnmrc bj ESR specwoscopy 1-adamamyl l-cyanoadamantyl and I-adamanlane~mmmyl free radicals are rormed m proporuons dependmg on wmperamrc The low-temperalure maJor producl I-cyanoadamantyl wansforms upon hearmg mto Ihe rmrmnyl free radical which can be used as a spin label for studymg molecular dynamics m glassy cryslalhnc I-cyanoadamantane