Intramolecular Dynamics of 1,2,3-Trifluorobenzene Radical Anions As Studied by OD ESR and Quantum-Chemical Methods
β Scribed by Barlukova, Maria M.; Beregovaya, Irina V.; Vysotsky, Victor P.; Shchegoleva, Lyudmila N.; Bagryansky, Victor A.; Molin, Yuri N.
- Book ID
- 120866664
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 155 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
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Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics