Long fluorescence lifetime of pyrazine vapors
โ Scribed by F. Lahmani; A. Frad; A. Tramer
- Book ID
- 103011926
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 589 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
By the study of the pressure dependence of the fluorescence and phosphorescence yields of pyrazinc vapors in the pressure range of 10-z-10 torr it wns established that the fluorescence decay is not exponential but contains a long component (7 = 10-6-10-7 set) corresponding to the "dilution" of the singlet radiative properties in the dense manifold of tripiet levels. The phosphorescence is due exclusively to the coilisionally induced rela;ation from the quasi-stationary state to the pure triplet state.
๐ SIMILAR VOLUMES
Subnanase~nd fluorcsccnce hfetimes of pprazine-l~~ and da vapor in the produce of Srg (100 Tort) were me~ured by eacrtmg sekcrcd k3brattconaI levels m the Sl(n,z\*) stare-The Iiktimes for the viiromc levelsdue to the qoa viiratron
Fluorescence-excitation and quantum-yield spectra were measured along the rotational contours of the O-O and lOa: bands of pyrazme and the O-O band of pyrimidme in the vapor phase at low pressure. A marked variation in quantum yield was observed. The yield spectra for the O-O bands exhiiit a very sh