Location of interstitial deuterium in TaD0.067 by channelling
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 160 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0042-207X
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β¦ Synopsis
investigation of the surface diffusion of oxygen on W(110). The vibrating electrode consists of a wire of 6 pm diameter which can be moved across the surface at a distance of 15 pm. The local work function profile is converted to the corresponding concentration profile by a calibration curve obtained by Auger spectroscopy. The evaluation achieved by the Boltzmann-Matano analysis yields a concentration dependent diffusion coefficient with an activation energy of 27 f 2 kcal. The concentration dependence can qualitatively be explained by the known adsorption properties of this adsorbate-substrate system.
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Time-of-flight neutron diffraction has been used to measure the dilation of h.c.p. Zr by interstitial deuterium at 727 and 777 K. The dilation per atom of D is 2.78 A3, and the partial molal volume is 1.67 cm3/mol. The lattice strain in the (c)-direction is 1.65 times greater than in the (a)-directi