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Living radical polymerization through the use of iniferters: Controlled synthesis of polymers

✍ Scribed by T. Otsu; T. Matsunaga; A. Kuriyama; M. Yoshioka

Book ID
107754206
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
651 KB
Volume
25
Category
Article
ISSN
0014-3057

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A novel polyurethane iniferter synthesized from 1,1,2,2-tetraphenyl-1,2ethane diol and toluene diisocyanate has been used to polymerize styrene through a "livingÏ radical mechanism. A rate equation (R p P [styrene]1Γ•1 [polyurethane iniferter]0Γ•93) and overall activation energy (E a \ 99 kJ mol~1) ha