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Living Radical Polymerization of N , N -Dimethylacrylamide with RuCl 2 (PPh 3 ) 3 -Based Initiating Systems 1

โœ Scribed by Senoo, Masahide; Kotani, Yuzo; Kamigaito, Masami; Sawamoto, Mitsuo


Book ID
121264468
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
107 KB
Volume
32
Category
Article
ISSN
0024-9297

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Well-deยฎned polystyrenes with an a-C(CH 3 ) 2 (CN) and an v-chlorine atom end-groups, and narrow polydispersity (M n = 3000ยฑ4000 g mol ร€1 , M w /M n = 1.3ยฑ1.4) have been synthesized by a radical polymerization process using 2,2'-azobisisobutyronitrile(AIBN)/FeCl 3 /PPh 3 initiation system. When the