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Amine Additives for Fast Living Radical Polymerization of Methyl Methacrylate with RuCl 2 (PPh 3 ) 31

✍ Scribed by Hamasaki, Shinya; Kamigaito, Masami; Sawamoto, Mitsuo


Book ID
126417119
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
98 KB
Volume
35
Category
Article
ISSN
0024-9297

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The bulk polymerization of methyl methacrylate (MMA) initiated with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS) was studied. This polymerization showed some "living" characteristics; that is, both the yield and the molecular weight of the resulting polymers increased with reaction time, and th